Absorption and Pleochroism
Some minerals selectively absorb certain wavelengths of light, and the
combination of wavelengths that pass through can give the mineral colour
observable in plane polarized light. If the selective absorption
differs with orientation of the crystal, the absorption colours change
with orientation. This phenomenon is termed pleochroism. Unless
the mineral is oriented with an optic axis in the vertical position, pleochroic
minerals change colour as the mineral is rotated in plane polarized light.
Uniaxial minerals can have two pleochroic colours, and biaxial minerals
can have three, corresponding to the principal vibration directions of
the mineral. Images A and B (rotated 90 degrees relative to one another)
show grains of biotite that illustrate pleochroism
in shades of pale yellow-brown (dominant in A) to red-brown (dominant in
B). In C and D (rotated 90 degrees relative to one another), hornblende
grains in a variety of orientations show three different colours (emerald
green, olivine green/brown, and pale yellow), which differ for individual
grains in the two images. If only the percent of light transmitted
varies with orientation, and not the colour (a function of the combination
of wavelengths transmitted), the colour remains the same during rotation
of the grain, but its intensity changes, and one sees darker or lighter
versions of the same colour. This is type of absorption is not true
pleochroism, and is a property of the mineral tourmaline.
All fields of view are 2.2 mm across and in ppl. |